Discover hydrogen fuel cell electric vehicles, producing hydrogen, electrolysis hydrogen, chlor-alkali hydrogen, SMR hydrogen, SMR-CCS hydrogen, coal or lignite hydrogen, and pyrolysis hydrogen, and explore the considerations when adopting FCEVs.
This section covers the possibility of using hydrogen fuel cell vehicles in your fleet.
As discussed in the options for powering a zero or ultra-low emission fleet page, hydrogen has the potential to make up for battery electric’s driving range constraints. This is because it offers a greater driving range and faster refuelling.
However, there is a limited availability of hydrogen vehicles on the market and limited coverage of hydrogen refuelling stations in Scotland.
This section aims to provide you with the information to consider whether hydrogen fuel cell vehicles may be a suitable option for some of your vehicles. There is still not enough information available for us to give specific vehicle options, and cost and emission savings.
Hydrogen is the lightest and most abundant element in the universe and contains more energy per unit of weight than any fossil fuel. It can be produced by breaking water apart with electrical power (electrolysis) or cracking fossil fuels with steam (steam methane reforming). There are zero tailpipe emissions when using hydrogen in a fuel cell vehicle. This means hydrogen production is the biggest contributor to the total emissions. Methods of creating hydrogen are listed below.
Although hydrogen has the highest energy density on a weight basis, it is not highly energy dense by volume. This means that for storage and distribution, it must be stored either as a cryogenic liquid, or more commonly as a high-pressure gas. For use in vehicles, hydrogen is generally stored as a gas at either 350 or 700 bar pressure, in tanks.
In a fuel cell, the hydrogen undergoes an electrochemical reaction, where its single proton and electron are split. The movement of the electrons through the circuit creates electricity, and the hydrogen proton, electron, and oxygen from the air are then combined to form water. As this is an electrochemical process, there are no by-products. The only output is the water produced. In a fuel cell electric vehicle (FCEV), there is an additional small battery, which the fuel cell recharges, and the battery directly controls the vehicle motors (and can make use of regenerative braking).
Hydrogen can also be combusted like a fossil fuel. However, this process is highly inefficient and produces NOx as a by-product, which is an air pollutant. We wouldn’t recommend using hydrogen in this way for vehicle use.
The main advantage of hydrogen over battery electric is the fuel energy density and the quick refuelling time. Together, these mean that with a developed refuelling system, FCEVs could overcome the range barrier in some applications.
The methods for hydrogen creation are often referred to by colour. However, there is no recognised standard for this colour coding, so it’s vital always to verify your hydrogen’s specific source and all the inputs used to produce it. For example, ‘green hydrogen’ generally refers to hydrogen produced by electrolysis, but the emissions produced will vary widely depending on the source of the electricity. We’ll refer to the creation process rather than a colour to avoid confusion. We’ve also listed some of the more common colours below, however this may not match other documents.
Two electrodes pass the direct current through the water when using electricity to split hydrogen from water. This causes an oxidation-reduction reaction, producing hydrogen and oxygen.
The sustainability of electrolysis hydrogen depends on the electricity source. Most commonly, this would be the national grid. Like battery electric vehicles (BEVs), this can be up to 100% zero emission if the electricity is produced locally from a renewable energy source like wind.
The process is inefficient, which results in a 30-35% energy loss and requires large quantities of pure water (around 15-30 litres per kg of hydrogen). This inefficiency can be reduced (Kumar & Himabindu, 2019). However, the technology has yet to reach the mass market. This is still the most sustainable way of producing hydrogen and can be produced with zero emissions. To be truly sustainable the electricity needs to be produced from renewable sources. But this also needs to be excess electricity that would have been curtailed if it wasn’t used to produce hydrogen.
Electrolysis of sodium chloride (NaCl) solution (typically brine). This is mainly used to create chlorine (Cl2). However, hydrogen (H2) and sodium hydroxide (NaOH) are also produced as by-products.
The chlor-alkali sector produces over a quarter of a million tonnes of hydrogen as a by-product of chlorine production. However, 10-15% of this is currently unused (Euro Chlor, 2021). This production method is limited by the chlorine market but may become more widespread if the price of hydrogen overtakes chlorine.
Chlor-alkali hydrogen as produced through electrolysis, has similar sustainability considerations and caveats to electrolysis (green) hydrogen and is dependant largely on the source of electricity. There is a small amount of further energy required to treat the hydrogen and other outputs. However, this process is still more sustainable and less energy intensive compared to SMR (Lee et al, 2018).
Steam methane reformation (SMR) is where methane from natural gas is heated with steam to produce carbon dioxide and hydrogen. This process can also use ethanol, propane or gasoline.
This remains one of the most inexpensive and widespread methods of making hydrogen. Over 95% of the world’s hydrogen is produced by SMR. However, for every tonne of hydrogen produced, around 9-10 tonnes of CO2 are released (Rapier 2020). If you choose to adopt hydrogen vehicles, it’s essential that SMR does not produce the hydrogen you source without CCS.
SMR with carbon capture and storage (CCS). Hydrogen is produced through SMR, and the CO2 emissions are ‘captured’ at source after the reformation process.
The sustainability of SMR-CCS hydrogen is dependent on the proportion of carbon that can be captured. It is important to note that not all CO2 is captured. To be viable as a low emission fuel, the Committee on Climate Change (2018) specifies that over 95% of CO2 needs to be captured and stored. However, there are no large scale SMR-CCS plants operating today that are achieving this level. For example, one of the largest SMR-CCS plants, Shell’s Quest SMR-CCS plant in Alberta, Canada, captures just 48% of stack emissions (Global Witness 2022).
Coal and lignite hydrogen is made by gasification and is among the most polluting hydrogen-making methods.
Pyrolysis hydrogen is relatively new and yet to be produced at scale. It generates hydrogen from methane from biogas with carbon produced in a solid state, removing the need for CCS. This means it is comparable to SMR-CCS hydrogen.
Natural hydrogen can be found occurring in subsurface reservoirs. However, this is rare and often difficult to extract.
The driving range of FCEVs are less of a constraint compared to BEVs. However, there is a limited variety of hydrogen vehicles compared to battery electric. This can only be resolved when the market matures.
A key consideration is how your hydrogen will be produced. As covered in the section above, only hydrogen made through electrolysis powered by excess renewable electricity is truly zero emission. All other forms of producing hydrogen have varying (and sometimes high) levels of upstream emissions associated with their production.
There are currently very few hydrogen refuelling stations in the UK, so you’ll likely have to store hydrogen for vehicles at your depots. You’ll have to decide whether to produce your own hydrogen on-site or have it delivered to your depot. Manufacturing hydrogen on-site using an electrolyser could be a viable option. However, there is around a 35% loss in energy during electrolysis. If you combine this with the further energy losses in the vehicle fuel cell and power train losses (outlined in table 16), you’d need over double the electricity to drive the same mileage compared to charging a BEV directly. Electrolysis requires approximately 15-30 litres of pure water per kg of hydrogen, so this would also either have to be sourced or purified on-site.
Another consideration is that while hydrogen is very energy dense on a weight basis, allowing for greater driving range, the well-to-wheel efficiency is much lower than internal combustion engine (ICE) vehicles, BEVs and vehicles running on biofuels.
FCEV HDVs are four to six times less energy efficient than BEVs on a well-to-wheel basis (Zemo, 2021). This means that, no matter how your hydrogen is produced, there will be a far greater energy loss compared to other methods of powering your fleet.
This inefficiency, paired with the higher unit cost of hydrogen, makes it an expensive zero emission option (as outlined in table 16). This shows that the fuel cost of hydrogen makes it the most expensive fuel to travel an equivalent distance, compared with diesel or battery electric.
Because of the energy loss well-to-wheel of FCEVs, and the greater maturity of the BEV market, we recommend adopting BEVs where possible. However, don’t rule out hydrogen for fleet segments that are harder to decarbonise. For example, if your fleet regularly covers longer driving ranges.
Fuel type | Units | Cost/unit | Cost | Fuel kWh | Fuel cell loss | Power train loss | Wheel kWh |
---|---|---|---|---|---|---|---|
Hydrogen | kg | £12.50 (1) | £12.50 | 33 | 30% | 8% | 20 |
Diesel | litres | £1.46 (2) | £8.12 | 58 | - | 65% | 20 |
Electricity | kWh | £0.22 (3) | £5.27 | 24 | - | 16% | 20 |
Table 16 – Cost comparison of different fuels. This table compares 1kg of hydrogen (equating to 33kWh of energy) to the costs to deliver the same kWh to the wheels by diesel or battery electric. With the losses through the fuel cell and in the power train in a hydrogen vehicle, roughly 20kWh of the original 33kWh (energy stored as hydrogen) reaches the wheels.
The figure of 20kWh delivered to the wheels equates roughly to 65 miles driven in a car or 11 miles in an HDV. Working back from this figure of 20kWh delivered to the wheels, using the efficiency of BEVs and diesel vehicles, the required fuel kWh can be calculated. Using the cost per unit of fuel, the relative costs can be calculated for driving the equivalent distance using each fuel type.